Category: fluorescent lamps

Does the size of the bulb affect its intensity?

The intensity of a normal fluorescent light bulb is determined by how many times each second (1) a mercury atom can absorb energy in a collision and emit a photon of ultraviolet light and (2) a phosphor particle can absorb a photon of ultraviolet light and emit a photon of visible light. The first rate depends on how much current and electrical power can flow through the tube, which in turn depends on (A) the geometry of the tube and (B) the density of mercury vapor inside. As for (A), the long, thin tube seems to be the best geometry choice for a low voltage (120V) tube, producing a certain amount of ultraviolet light per cubic centimeter of volume. The longer or fatter the tube, the more electrical power it will require and the more ultraviolet light it will produce. As for (B), at room temperature, the density of mercury vapor is just about right. In very cold weather, the density drops quite low and the bulb becomes dim (thus fluorescents are not recommended for outdoor use in cold climates). Finally, the second rate (conversion to visible light) depends on the coating of phosphors on the inside of the tube. A tube that is too fat will send too much ultraviolet light at the phosphors and they will become inefficient. So a long thin tube is a good choice again. Each region of tube surface converts the light from a relatively small volume of mercury gas. Overall, the intensity of the bulb scales roughly with the volume of the tube. Big tubes emit more light than little tubes. One of the challenges facing fluorescent lamp manufacturers is in making small tubes emit lots of light. To replace an incandescent lamp with a miniaturized fluorescent, that miniaturized fluorescent must emit lots of light for its size. They’re getting better every year, but they aren’t bright enough yet.

Why do fluorescent tubes explode if broken (is it the compression of the gas)?

Fluorescent tubes operate at very low pressure; roughly 1/1000th of an atmosphere. They do not explode when broken; they implode. The atmospheric pressure surrounding the tube crushes it as soon as it begins to crack. The tube shape of a typical fluorescent tube is chosen because it can withstand the enormous compressive forces of the atmosphere better than most other shapes.

How do “forbidden transitions” become less forbidden as pressure builds?

For an atom to determine that it cannot make a particular transition (that its electron cannot move from one particular orbital to another), it must first “test the water”. The atom effectively tries to make particular transition but finds that this transition is not possible. However, if the atom experiences a collision during the test period, the atom may “accidentally” undergo the forbidden transition. It is as though the atom was prevented from canceling the experiment.

Why do many fluorescent lamps blink before they come on?

The lamp first heats the filaments in its electrodes red hot so that they begin to emit electrons and then tries to start a discharge across the lamp. If there are not enough electrons leaving the electrodes to sustain a steady discharge, the lamp will blink briefly but will not stay on. The lamp will try again; first heating its filaments and then trying to start the discharge. The lamp may blink several times before the discharge becomes strong enough to keep the electrodes hot and sustain the discharge.

How do phosphors change the light from ultraviolet to visible?

They absorb the light and light energy by transferring electrons from low energy valence levels to high-energy conduction levels. These electrons wander about inside the phosphors briefly, losing energy as heat, and then fall back down to empty valence levels. Since they have lost some of their energy to heat, the light that they emit has less energy than the light they absorbed. Incoming ultraviolet light is converted to outgoing visible light.

Why do mercury lamps without phosphors emit visible light at high pressure? What are the “forbidden” transitions?

At low pressure, a mercury lamp emits mostly 254-nanometer ultraviolet light. That light is created when an electron in the mercury atom goes from its lowest excited orbital to its ground (normal) orbital. The other wavelengths of light emitted by the low-pressure lamp are weak and widely spaced in wavelength. An electron must sent into a very highly excited orbital in order to emit one of these other wavelengths. But at high pressure, mercury atoms have trouble sending their favorite 254 nanometer light out of the lamp. Whenever one of the atoms emits a particle of 254-nanometer light (moving its electron from the first excited orbital to the ground orbital), another nearby atom absorbs that particle of light (moving its electron from the ground orbital to the first excited orbital). As a result the 254-nanometer light cannot escape from the lamp; it becomes trapped in the mercury gas! Instead, the atoms begin to send their energy out of the lamp by concentrating on radiative transitions between highly excited orbitals and that lowest excited orbital. These wavelengths become more common in the light emission from the lamp as its pressure rises. But some radiative transitions that are forbidden at low pressure (that cannot occur because an electron is not able to move from one particular excited orbital to another particular excited orbital) become allowed at high pressure. Collisions break many of the rules that govern atomic behavior, allowing otherwise forbidden events to occur. In the case of the mercury lamp, collisions at high pressure permit the mercury atoms to emit wavelengths of light that they cannot emit a low pressure when collisions are rare.

How does a fluorescent light work?

A fluorescent lamp consists of a gas-filled glass tube with an electrode at each end. This lamp emits light when a current of electrons passes through it from one electrode to the other and excites mercury atoms in the tube’s vapor. The electrons are able to leave the electrodes because those electrodes are heated to high temperatures and an electric field, powered by the electric company, propels them through the tube. However, the light that the mercury atoms emit is actually in the ultraviolet, where it can’t be seen. To convert this ultraviolet light to visible light, the inside surface of the glass tube is coated with a fluorescent powder. When this fluorescent powder is exposed to ultraviolet light, it absorbs the light energy and reemits some of it as visible light, a process called “fluorescence.” The missing light energy is converted to thermal energy, making the tube slightly hot. By carefully selecting the fluorescent powders (called “phosphors”), the manufacturer of the light can tailor the light’s coloration. The most common phosphor mixtures these days are warm white, cool white, deluxe warm white, and deluxe cool white.

The only other significant component of the fluorescent lamp is its ballast. This device is needed to control the current flow through the tube. Gas discharges such as the one that occurs inside the lamp are notoriously unstable—they’re hard to start and, once they do start, tend to become too intense. To regulate the discharge, the ballast controls the amount of current flowing through the tube. In most older lamps, this control is done by an electromagnetic device called an inductor. An inductor opposes current changes and keeps a relatively constant current flowing through the tube (although that current does stop and reverse directions each time the power line current reverses directions — 120 times a second or 60 full cycles, over and back, in the United States). Some modern fluorescent lamps use electronic ballasts—sophisticated electronic controls that regulate current with the help of transistor-like components.

Why does a fluorescent bulb sometimes appear blue, especially right before it burns out?

I’m not aware of any tendency to change colors as it begins to burn out, but many fluorescent bulbs are relatively blue in color. The phosphor coatings used to convert the mercury vapor’s ultraviolet emission into visible light don’t create pure white. Instead, they create a mixture of different colors that is a close approximation to white light. There are a number of different phosphor mixtures, each with its own characteristic spectrum of light: cool white, deluxe cool white, warm white, deluxe warm white, and others. The cool white bulbs are most energy efficient but emit relatively bluish light. This light gives the bulbs a cold, medicinal look. The warm white bulbs are less energy efficient, but more pleasant to the eye.